cis-Bis(nitrato-κ2 O,O′)bis(triethylphosphine oxide-κO)nickel(II)
نویسنده
چکیده
In the title compound, [Ni(NO(3))(2)(C(6)H(15)OP)(2)], the Ni(II) ion, lying on a crystallographic twofold axis, adopts a distorted octa-hedral coordination, consisting of O-donor atoms of two symmetry-related triethyl-phospine oxide and two bidentate nitrate ligands.
منابع مشابه
Bis[(2-aminophenyl)methanol-κ2 O,N]bis(nitrato-κO)manganese(II)
In the title compound, [Mn(NO(3))(2)(C(7)H(9)NO)(2)], the Mn(II) atom (site symmetry 2) is coordinated by two N,O-bidentate (2-amino-phen-yl)methanol ligands and two monodentate nitrate anions in a distorted cis-MnN(2)O(4) octa-hedral coordination geometry. In the crystal, N-H⋯O, O-H⋯O and C-H⋯O hydrogen bonds help to establish the packing.
متن کاملA 2:1 cocrystal of the cis and trans isomers of bis[1,1,1,5,5,5-hexafluoropentane-2,4-dionato(1−)-κ2 O,O′]bis(4-phenylpyridine N-oxide-κO)copper(II)
The title compound is a co-crystal of the cis and trans isomers, namely cis-bis-[1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato(1-)-κ(2)O,O']bis-(4-phenyl-pyridine N-oxide-κO)copper(II)-trans-bis-[1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato(1-)-κ(2)O,O']bis(4-phenyl-pyridine N-oxide-κO)copper(II) (2/1), [Cu(C(5)HF(6)O(2))(2)(C(11)H(9)NO)(2)]. In both isomers, the coordination geometry of the Cu(2+...
متن کاملBis(nitrato-κO)bis[4,4,5,5-tetramethyl-2-(5-methyl-1H-imidazol-4-yl-κN 3)-2-imidazoline-1-oxyl 3-oxide-κO]nickel(II)
In the centrosymmetric mononuclear title complex, [Ni(NO(3))(2)(C(11)H(17)N(4)O(2))(2)], the Ni(II) atom displays a distorted octa-hedral coordination geometry and is six-coordinated by two N,O-bidentate nitronyl nitroxide radical ligands and two monodentate nitrate anions.
متن کاملBis[(2-aminophenyl)methanol-κ2 N,O]bis(nitrato-κO)zinc(II)
In the title compound, [Zn(NO(3))(2)(C(7)H(9)NO)(2)], the Zn(II) atom, lying on a twofold rotation axis, is six-coordinated in a distorted octa-hedral geometry by two N atoms and two O atoms from two (2-amino-phen-yl)methanol ligands and two O atoms from two monodentate nitrate anions. Inter-molecular N-H⋯O, O-H⋯O and C-H⋯O hydrogen bonds stabilize the crystal structure.
متن کاملcatena-Poly[[bis(nitrato-κO)cadmium]bis[μ-1,4-bis(pyridin-3-ylmethoxy)benzene-κ2 N:N′]]
In the title compound, [Cd(NO(3))(2)(C(18)H(16)N(2)O(2))(2)](n), the six-coordinated Cd(II) ion is located on an inversion center and has a distorted octa-hedral environment defined by four N atoms from four 1,4-bis-(pyridin-3-ylmeth-oxy)benzene ligands and two O atoms from two nitrate anions. The ligands link the Cd(II) ions into a ribbon-like structure running along [201]. One O atom of the n...
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